| Bayer Leverkusen 2 - 0 Fortuna Dusseldorf | 2019-02-17 17:00:00 |
| Villarreal 3 - 0 Sevilla | 2019-02-17 17:30:00 |
| FC Shakhtar Donetsk 2 - 2 Eintracht Frankfurt | 2019-02-14 20:00:00 |
| Galatasaray 1 - 2 Benfica | 2019-02-14 17:55:00 |
| Rennes 3 - 3 Real Betis | 2019-02-14 17:55:00 |
| Juventus 3 - 0 Frosinone | 2019-02-15 19:30:00 |
| Celtic FC 0 - 2 Valencia | 2019-02-14 20:00:00 |
| FC Zurich 1 - 3 Napoli | 2019-02-14 20:00:00 |
| Saint Etienne 0 - 1 Paris Saint Germain (PSG) | 2019-02-17 20:00:00 |
| Malmo FF 1 - 2 Chelsea | 2019-02-14 20:00:00 |
| Inter Milan 2 - 1 Sampdoria | 2019-02-17 17:00:00 |
| Napoli 0 - 0 Torino | 2019-02-17 19:30:00 |
| Queens Park Rangers (QPR) 0 - 1 Watford | 2019-02-15 19:45:00 |
| Sporting Lisbon 0 - 1 Villarreal | 2019-02-14 20:00:00 |
| Lyon 2 - 1 Guingamp | 2019-02-15 19:45:00 |
| Lazio 0 - 1 Sevilla | 2019-02-14 17:55:00 |
| Olympiakos Piraeus 2 - 2 Dynamo Kyiv | 2019-02-14 17:55:00 |
| FC Krasnodar 0 - 0 Bayer Leverkusen | 2019-02-14 17:55:00 |
| Valencia 0 - 0 RCD Espanyol | 2019-02-17 15:15:00 |
| Eibar 2 - 2 Getafe | 2019-02-15 20:00:00 |
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